Tetraaquabis[3-(2-pyridylsulfanyl)propionato N-oxide]nickel(II)
نویسندگان
چکیده
In the centrosymmetric title compound, [Ni(C(8)H(8)NO(3)S)(2)(H(2)O)(4)], the Ni(II) ion, which lies on an inversion centre, is six coordinated by four water mol-ecules and two propionate O atoms from two 2-pyridylsulfanylpropionate N-oxide ligands, forming a slightly distorted octa-hedral geometry. An intra-molecular O-H⋯O hydrogen bond stabilizes the mol-ecular conformation. The crystal packing is consolidated by inter-molecular O-H⋯O and C-H⋯O hydrogen bonding.
منابع مشابه
Tetraaquabis[3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazolido]nickel(II) dihydrate
In the title compound, [Ni(C(12)H(8)N(5))(2)(H(2)O)(4)]·2H(2)O, the Ni(II) atom is coordinated by the two N atoms [Ni-N = 2.094 (3) Å] and four O atoms [Ni-O = 2.063 (3)-2.083 (2) Å] in a distorted octa-hedral geometry. The mol-ecule is centrosymmetric and the Ni(II) atom is located on an inversion center. Inter-molecular O-H⋯N and O-H⋯O hydrogen bonds link the complex into a three-dimensional ...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009